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Improved centrifugal and hyperfine analysis of ND2H and NH2D and its application to the spectral line survey of L1544

2021

Abstract Quantifying molecular abundances of astrochemical species is a key step towards the understanding of the chemistry occurring in the interstellar medium. This process requires a profound knowledge of the molecular energy levels, including their structure resulting from weak interactions between nuclear spins and the molecular rotation. With the aim of increasing the quality of spectral line catalogs for the singly- and doubly-deuterated ammonia (NH2D and ND2H), we have revised their rotational spectra by observing many hyperfine-resolved lines and more accurate high-frequency transitions. The measurements have been performed in the submillimeter-wave region (265–1565 GHz) using a fr…

Rotational spectroscopy010402 general chemistry01 natural sciencesStarless coreSpectral linelaw.inventionDeuterium fractionationAmmoniaInterstellar mediumlaw0103 physical sciencesPhysical and Theoretical ChemistryHyperfine structureAstrophysics::Galaxy AstrophysicsSpectroscopyLine (formation)010304 chemical physicsSpectrometerAtomic and Molecular Physics and OpticsSynchrotron0104 chemical sciencesComputational physicsInterstellar mediumDeuteriumHyperfine structureRotational spectroscopyJournal of Molecular Spectroscopy
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